Painting & Coating Industry (PCI) logo Powder coating summit logo
  • Sign In
  • Create Account
  • Sign Out
  • My Account
  • NEWS
  • PRODUCTS
  • MATERIALS
  • TECHNOLOGIES
  • FINISHING
  • RESOURCES
  • EVENTS
  • DIRECTORIES
  • EMAGAZINE
  • CONTACT
cart
facebook twitter linkedin youtube
  • NEWS
  • Latest News
  • Market Trends & Reports
  • Price Alerts
  • Subscribe to eNewsletters
  • Global Top 10/ PCI 25
  • Weekly Featured Article
  • COATLE Word Game
  • PRODUCTS
  • Product News
  • Must See Products and Services
  • MATERIALS
  • Additives
  • Resins/Polymers
  • Pigments
  • Equipment
  • Distributors
  • TECHNOLOGIES
  • Adhesives
  • Architectural Coatings
  • Industrial Coatings
  • Nanotechnology
  • Powder Coatings
  • Solventborne
  • Special Purpose Coatings
  • Sustainability
  • UV Coatings
  • Waterborne
  • Waterborne
  • FINISHING
  • Finishing News
  • Finishing Technologies
  • Finishing Equipment
  • RESOURCES
  • Columns
  • Blogs
  • Coatings Supplier Handbook
  • Podcasts and Videos
  • PCI Store
  • eBooks
  • Sponsor Insights
  • White Papers
  • COATLE Word Game
  • Columns
  • Ask Joe Powder
  • Did you know?
  • Distribution Dive
  • Focus on Canada
  • Formulating With Mike
  • Innovation Insights
  • Moody's Coatings Conundrums
  • Powder Coating Perspectives
  • Target the Market
  • TiO2 Insider
  • Blogs
  • Editor's Viewpoint
  • Industry Insights
  • Podcasts and Videos
  • COAT-IT! Podcast
  • Videos/PCI TV
  • EVENTS
  • Coatings Trends & Technologies Summit
  • Paint and Coatings Academy
  • Webinars
  • Calendar of Events
  • Lifetime Achievement Award
  • DIRECTORIES
  • Buyer's Guide
  • Equipment Directory
  • Materials Directory
  • EMAGAZINE
  • Current Issue
  • eMagazine Archive
  • China Issue Archive
  • Editorial Advisory Board
  • CONTACT
  • Contact Us
  • Advertise
  • Subscribe to eMagazine
  • Subscribe to eNewsletters
Painting & Coating Industry (PCI) logo Powder coating summit logo
search
cart
facebook twitter linkedin youtube
  • Sign In
  • Create Account
  • Sign Out
  • My Account
Painting & Coating Industry (PCI) logo Powder coating summit logo
  • NEWS
    • Latest News
    • Market Trends & Reports
    • Price Alerts
    • Subscribe to eNewsletters
    • Global Top 10/ PCI 25
    • Weekly Featured Article
    • COATLE Word Game
  • PRODUCTS
    • Product News
    • Must See Products and Services
  • MATERIALS
    • Additives
    • Resins/Polymers
    • Pigments
    • Equipment
    • Distributors
  • TECHNOLOGIES
    • Adhesives
    • Architectural Coatings
    • Industrial Coatings
    • Nanotechnology
    • Powder Coatings
    • Solventborne
    • Special Purpose Coatings
    • Sustainability
    • UV Coatings
    • Waterborne
    • FINISHING
      • Finishing News
      • Finishing Technologies
      • Finishing Equipment
    • RESOURCES
      • Columns
        • Ask Joe Powder
        • Did you know?
        • Distribution Dive
        • Focus on Canada
        • Formulating With Mike
        • Innovation Insights
        • Moody's Coatings Conundrums
        • Powder Coating Perspectives
        • Target the Market
        • TiO2 Insider
      • Blogs
        • Editor's Viewpoint
        • Industry Insights
      • Coatings Supplier Handbook
      • Podcasts and Videos
        • COAT-IT! Podcast
        • Videos/PCI TV
      • PCI Store
      • eBooks
      • Sponsor Insights
      • White Papers
      • COATLE Word Game
    • EVENTS
      • Coatings Trends & Technologies Summit
      • Paint and Coatings Academy
      • Webinars
      • Calendar of Events
      • Lifetime Achievement Award
    • DIRECTORIES
      • Buyer's Guide
      • Equipment Directory
      • Materials Directory
    • EMAGAZINE
      • Current Issue
      • eMagazine Archive
      • China Issue Archive
      • Editorial Advisory Board
    • CONTACT
      • Contact Us
      • Advertise
      • Subscribe to eMagazine
      • Subscribe to eNewsletters

    An Accelerated Test Procedure for the Evaluation of Acid-Etch Resistance of Coatings

    July 31, 2001
    Acid etch, or environmental etch, is a defect that can occur in any exterior paint finish.1-9 However, it is a major concern for the automotive industry. The result of acid etch may appear as rings on a car's finish. These rings may seem like water spots, but in actuality, damage has been done to the finish, so washing does not remove the rings. Certain geographical areas are affected more than others - areas adjacent to heavily industrialized cities usually have high incidents of acid etch complaints.

    Historically, isocyanate-crosslinked coatings outperformed melamine-crosslinked coatings for acid-etch resistance. However, melamine-crosslinked coatings10 are still in use because they are more cost effective and have better mar resistance.11, 12

    This article details an accelerated acid-etch test. A similar test has been mentioned by Gregorovich and Hazan.1 They compared the acid-etch test to actual Jacksonville test data. It has been the automotive industry that has primarily studied and tried to eliminate this paint defect.

    This relatively simple test yields a pair of values, the minimum spot temperature (MST) and the scaled acid value. These values are used to rank the severity of the acid damage to a coating. The test procedure uses a BYK-Gardner gradient oven. In addition, steel panels (4" x 22.5" x 0.032") are required (these are the standard size panels used in the gradient oven). To make the comparison of coatings in this brief study easier, one acrylic polyol and either an isocyanate resin or a melamine resin were used as the crosslinker.

    Procedure

    1. Prepare a panel for testing by coating a film on a 4" x 22.5" x 0.032" steel (polished) panel using the formulation and cure parameters for the specific material. Sometimes a post cure time period is recommended before the acid-etch test is run.

    2. Set the gradient oven for a 30-minute time cycle using a temperature range of 35-75?C as a continuous gradient. The oven has 45 individual temperature zones.

    3. Gradient oven supplies include pre-pasted paper strips with evenly spaced measuring points numbered from one through 45 over a 20" length. These correspond to the 1-45 gradient temperature zones. Affix the strip along the length of the panel near an edge. Directly opposite each number on the strip, use a pipette to dispense approximately two drops (0.4 grams) of a 10% sulfuric acid solution (or other solution desired). Move the panel with the drops gently onto the preheated gradient surface for the 30 minutes.

    4. At the end of the 30 minutes, remove the panel and obtain the printout of the actual temperature of each measuring point. Rinse off any remaining etching material with tap water. Using a facial tissue, wipe off any excess water. Spray the panel with "Super-Clear lens cleaner" from AOSafety Products and wipe it off using a clean tissue.

    5. Examine the panel under a good light source. Tilt the panel back and forth and note the temperature corresponding to the first visually etched spot, no matter how faint. Record the temperature for that point from the printout. This value is the minimum spot temperature (MST). To make the faintest rings visible, exhale, as if cleaning glasses, over the rings where "grade 1" damage starts. (This spot may disappear from visual sight in a short period of time.) Grade each using a scale of 1 to 5, with 5 being the worst:

      grade 1 - barely visible
      grade 2 - complete circle visible, but not filled in
      grade 3 - totally visible and filled circle
      grade 4 - blistering evident
      grade 5 - removal of film to bare panel
    6. Sum all the grades. This value is the total acid effect. A maximum of 225 is possible if all spots etch through to the bare metal. To express acid resistance on a scale from 0.0 to 1.0, take this total number and divide it by the maximum (i.e., 97/225), and subtract the result from 1.0. This gives a scaled acid value [1.0-(97/225)]=0.57. A zero rating would be equal to a panel receiving a total acid effect of 225 (total failure) and a 1.0 rating would be equal to a panel not being affected by the acid at all.

    It is possible to do multiple tests of several solutions at the same time, noting which row of spots corresponds to each solution. Extra care is needed when the panel is placed into the oven so that the different solutions do not mix together. The figure shows an ordered series of test panels. The most affected panels are on the right.

    Results and Discussion

    Higginbottom, et al. compared the effect of the type of crosslink functionality, hydroxyl groups vs. carbamate groups, in melamine-containing coatings.2 They used an acrylic polyol and derivatized it to form an acrylic carbamate. The resulting coatings were examined and selected data is presented in Table 1.

    The data shows that this type of modification can produce a large enough effect that causes the scaled acid value to increase from 0.56 to 0.69. A minimum spot temperature (MST) of 50+ ?C and a scaled acid value of between 0.65 to 0.85 are common for coatings considered fairly resistant to the acid etch phenomenon.2

    In this study, the acrylic polyol used was Macrynal SM 515/70BAC.13 Three variables were examined. The DFT (dry film thickness), the ratio of melamine resin to acrylic resin, and the crosslinker type were examined. The coating formulations and the acid etch results are shown in Table 2.

    The acid-etch values found for the 80/20 (acrylic/melamine) ratio coating indicate that this ratio produced a more acid resistant coating than the 75/25 ratio coating. Notice that the 2 mil coating did not significantly improve the acid-etch resistance as compared to the 1 mil coating. This demonstrates that as little as a 1 mil coating can have good acid-etch resistance. When the two different crosslinkers were compared, the melamine-crosslinked coating produced a slightly better acid-etch-resistant coating.

    This is not a surprising result. Melamine systems can be made to produce coatings with similar acid-etch resistance as isocyanate systems. The choice of the vehicle binder resin seems to be the key in producing a coating with improved acid etch resistance when using a melamine crosslinker. Acrylic resins modified with alkoxysilane groups1,3 or with carbamate functionality2 are two technologies used to increase acid-etch resistance.

    Conclusion

    A simple procedure for testing the acid-etch resistance of coatings was presented. As with most accelerated test procedures, this test should only be used as a screening tool. This article also mentioned ways to improve the acid-etch resistance of coatings. Obviously, all the properties of a coating must be considered before a paint system is chosen. Isocyanates were once the preferred crosslinker system used to produce coatings with good environmental etch resistance. Today, when suitable vehicle resins (or auxiliary crosslinkers) are used, a melamine resin is a viable crosslinker candidate for use in acid-etch resistant automotive coatings.

    References
    1. Gregorovich, B.V.; Hazan, I. Progress in Organic Coatings, 24 (1994), p. 131.
    2. Higginbottom, H.P.; Bowers, G.R.; Ferrell, P.E.; Hill, L.W. J. Coatings Technol., 71 (1999), p. 49.
    3. Hazan, I. "Low VOC-Super High Solids Clearcoats", Proceedings of the 7th Annual ESD Advanced Coatings Technology Conference, Detroit, Sept. 28-29, 1998.
    4. White, D.F.; Fornes, R.E.; Gilbert, R.D.; Speer, J.A. J. Applied Polymer Sci., 50 (1993), p. 541.
    5. Rodgers, W.R.; Garner, D.P.; Cheever, G.D. J. Coatings Technol., 70 (1998), p. 83.
    6. Skrovanek, D.J. J. Coatings Technol, 61 (1989), p. 31.
    7. Schmitz, P.J.; Holubka, J.W.; Xu, L. J. Coatings Technol., 72 (2000), p. 39.
    8. Holubka, J.W.; Schmitz, P.J.; Xu, L. J. Coatings Technol, 72 (2000), p. 77.
    9. Wolff, G.T.; Rodgers, W.R.; Collins, D.C.; Verma, M.H.; Wong, C.A. J. Air & Waste Mgmt. Assoc., 40 (1990), p. 1638.
    10. Coatings Technol. Handbook, 2nd ed., Satas, D.; Tracton, A.A. Eds., Marcel Deker Inc., 2000, pp. 669-675.
    11. Pourdeyhimi, B.; Wang, X.; Lee, F. European Coatings J., 4 (1999), p. 100.
    12. Courter, J.L.; Kamenetzky, E.A. European Coatings J., 7-8 (1999), p. 24.
    13. A styrene-acrylic polyol, Solutia Inc.

    Share This Story

    Looking for a reprint of this article?
    From high-res PDFs to custom plaques, order your copy today!

    Recommended Content

    JOIN TODAY
    to unlock your recommendations.

    Already have an account? Sign In

    • PCI-0724-Global10-Feature-1440.png

      2024 Global Top 10: Top Paint and Coatings Companies

      Who ranks on top? PCI’s annual ranking of the top 10...
      Global Top 10 and PCI 25
      By: Courtney Bassett
    • PCI-0724-PCI25-Feature-1440.png

      2024 PCI 25: Top Paint and Coatings Companies

      PCI's annual ranking of the top 25 North American paint...
      Paint and Coating Market Reports
      By: Courtney Bassett
    • pci1022-Kinaltek-Lead-1170.jpg

      A Novel Pigment Production Technology

      Following an extensive R&D program that demonstrated...
      Paint and Coating Pigments
      By: Jawad Haidar and Nitin Soni
    You must login or register in order to post a comment.

    Report Abusive Comment

    Subscribe For Free!
    • eMagazine
    • eNewsletter
    • Online Registration
    • Subscription Customer Service

    The Coatings Minute: Print Returns with PCI’s New Showcase Issue

    The Coatings Minute: Print Returns with PCI’s New Showcase Issue

    The Coatings Minute: Your Inside Look at PCInnovations

    The Coatings Minute: Your Inside Look at PCInnovations

    CTT Registration Now Open

    CTT Registration Now Open

    The Coatings Minute: Why Industry News Matters More Than Ever

    The Coatings Minute: Why Industry News Matters More Than Ever

    More Videos

    Sponsored Content

    Sponsored Content is a special paid section where industry companies provide high quality, objective, non-commercial content around topics of interest to the PCI audience. All Sponsored Content is supplied by the advertising company and any opinions expressed in this article are those of the author and not necessarily reflect the views of PCI or its parent company, BNP Media. Interested in participating in our Sponsored Content section? Contact your local rep!

    close
    • Modern arapartment complex painted in bright colors.
      Sponsored byEPS - Engineered Polymer Solutions

      Architectural Polymers Leading the Way in Coatings Innovation

    • paint sprayer in a workshop
      Sponsored byallnex

      Enabling Performance and Compliance: allnex Introduces a New Line of VOC Exempt Solvent-Borne Resins

    Popular Stories

    No. 3 AkzoNobel

    AkzoNobel to Close Two Manufacturing Sites

    A collage of products using non-PFAS

    A Surge in Non-PFAS Releases

    Default Aerospace Image

    PPG Plans Major Aerospace Facility



    PCI Buyers Guide

    Submit a Request for Proposal (RFP) to suppliers of your choice with details on what you need with a click of a button

    Start your RFP

    Browse our Buyers Guide for manufacturers and distributors of all types of coatings products and much more!

    Find Suppliers

    Events

    September 3, 2025

    Coatings Trends & Technologies Summit

    The Coatings Trends & Technologies (CTT) Summit is an annual conference for both liquid and powder coatings formulators and manufacturers to discuss innovations in coatings technology. This event combines high-quality technical presentations, a resource-rich exhibit hall, and dedicated networking opportunities to connect scientific minds, foster innovation, and cultivate game-changing new ideas!

    January 1, 2030

    Webinar Sponsorship Information

    For webinar sponsorship information, visit www.bnpevents.com/webinars or email webinars@bnpmedia.com.

    View All Submit An Event

    Poll

    Longest-running laboratory experiment

    What is the longest-running laboratory experiment?
    View Results Poll Archive

    Products

    CTT Summit Short Courses (Live 9/3/25)

    Coatings Trends & Technologies Summit is expanding its offerings with four short courses. These short courses will offer an extensive day of interactive learning.

    See More Products
    pci  webinar april 2025

    PCI CASE EBOOK

    Related Articles

    • Accelerated Acid Etch for Automotive Clearcoats - Part 2

      See More
    • Accelerated Acid Etch for Automotive Clearcoats

      See More
    • Evaluation of Scratch Resistance Test Methods for Organic Coatings

      See More
    ×

    Keep the info flowing with our eNewsletters!

    Get the latest industry updates tailored your way.

    JOIN TODAY!
    • RESOURCES
      • Advertise
      • Contact Us
      • Directories
      • Store
      • Want More
    • SIGN UP TODAY
      • Create Account
      • eMagazine
      • eNewsletters
      • Customer Service
      • Manage Preferences
    • SERVICES
      • Marketing Services
      • Reprints
      • Market Research
      • List Rental
      • Survey & Sample
    • STAY CONNECTED
      • LinkedIn
      • Facebook
      • Youtube
      • X (Twitter)
    • PRIVACY
      • PRIVACY POLICY
      • TERMS & CONDITIONS
      • DO NOT SELL MY PERSONAL INFORMATION
      • PRIVACY REQUEST
      • ACCESSIBILITY

    Copyright ©2025. All Rights Reserved BNP Media.

    Design, CMS, Hosting & Web Development :: ePublishing

    Painting & Coating Industry (PCI) logo Powder coating summit logo
    search
    cart
    facebook twitter linkedin youtube
    • Sign In
    • Create Account
    • Sign Out
    • My Account
    Painting & Coating Industry (PCI) logo Powder coating summit logo
    • NEWS
      • Latest News
      • Market Trends & Reports
      • Price Alerts
      • Subscribe to eNewsletters
      • Global Top 10/ PCI 25
      • Weekly Featured Article
      • COATLE Word Game
    • PRODUCTS
      • Product News
      • Must See Products and Services
    • MATERIALS
      • Additives
      • Resins/Polymers
      • Pigments
      • Equipment
      • Distributors
    • TECHNOLOGIES
      • Adhesives
      • Architectural Coatings
      • Industrial Coatings
      • Nanotechnology
      • Powder Coatings
      • Solventborne
      • Special Purpose Coatings
      • Sustainability
      • UV Coatings
      • Waterborne
      • FINISHING
        • Finishing News
        • Finishing Technologies
        • Finishing Equipment
      • RESOURCES
        • Columns
          • Ask Joe Powder
          • Did you know?
          • Distribution Dive
          • Focus on Canada
          • Formulating With Mike
          • Innovation Insights
          • Moody's Coatings Conundrums
          • Powder Coating Perspectives
          • Target the Market
          • TiO2 Insider
        • Blogs
          • Editor's Viewpoint
          • Industry Insights
        • Coatings Supplier Handbook
        • Podcasts and Videos
          • COAT-IT! Podcast
          • Videos/PCI TV
        • PCI Store
        • eBooks
        • Sponsor Insights
        • White Papers
        • COATLE Word Game
      • EVENTS
        • Coatings Trends & Technologies Summit
        • Paint and Coatings Academy
        • Webinars
        • Calendar of Events
        • Lifetime Achievement Award
      • DIRECTORIES
        • Buyer's Guide
        • Equipment Directory
        • Materials Directory
      • EMAGAZINE
        • Current Issue
        • eMagazine Archive
        • China Issue Archive
        • Editorial Advisory Board
      • CONTACT
        • Contact Us
        • Advertise
        • Subscribe to eMagazine
        • Subscribe to eNewsletters